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Автор L P Ingman
Автор M Punkkinen
Автор A H Vuorimaki
Автор E E Ylinen
Дата выпуска 1985-09-10
dc.description Effects of rotational tunnelling on the proton spin-lattice relaxation were studied in (NH<sub>4</sub>)<sub>2</sub>ZnCl<sub>4</sub> as functions of both temperature and the resonance frequency. Several tunnelling-related T<sub>1</sub> minima were found. At 20K the tunnel frequencies were deduced to be 13 MHz, 24.5 MHz, 37 MHz and 51.5 MHz corresponding to the separation between the nondegenerate and the doubly degenerated T levels, to the T-A splittings and to the E-A splitting, respectively. The smallest tunnel frequency (13 MHz) was observed to branch into two above 20K. The higher frequency branch could not be detected above 26K because of a broadening of the corresponding T<sub>1</sub> minimum. The broadening suggests a presence of two motions which was supported by experiments on the spin-lattice relaxation of the dipolar energy.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Proton spin-lattice relaxation and ammonium tunnelling in (NH<sub>4</sub>)<sub>2</sub>ZnCl<sub>4</sub>
Тип paper
DOI 10.1088/0022-3719/18/25/020
Print ISSN 0022-3719
Журнал Journal of Physics C: Solid State Physics
Том 18
Первая страница 5033
Последняя страница 5041
Аффилиация L P Ingman; Dept. of Phys. Sci., Turku Univ., Finland
Аффилиация M Punkkinen; Dept. of Phys. Sci., Turku Univ., Finland
Аффилиация A H Vuorimaki; Dept. of Phys. Sci., Turku Univ., Finland
Аффилиация E E Ylinen; Dept. of Phys. Sci., Turku Univ., Finland
Выпуск 25

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