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Автор M Weger
Автор N F Mott
Дата выпуска 1985-03-30
dc.description The 'classical' s-d scattering theory is applied to account for the anomalous temperature dependence of the resistivity in some intermetallic compounds, which possess very narrow peaks in the electronic density of states, due to d or f states. At temperatures where h(cross)/ tau <sub>e-ph</sub> approximately=J, where tau <sub>e-ph</sub> is the electron-phonon scattering time and J a hybridisation integral, the hybridisation is broken, and at higher temperatures the resistivity follows a linear rho =a+bT law. The temperature-independent part a is due to phonons scattering the d or f states, into which the s electrons (which carry most of the electric current) are scattered by the hybridisation integral J. The bT term is due to phonon scattering of the more itinerant s (or p) states into s states. This term does not saturate because the mean free path of the s electrons is still about 10 interatomic spacings, even at high temperatures. The thermoelectric power has a maximum when h(cross)/ tau <sub>e-ph</sub> approximately=J.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Breakdown of hybridisation at elevated temperatures in some intermetallic compounds
Тип lett
DOI 10.1088/0022-3719/18/9/005
Print ISSN 0022-3719
Журнал Journal of Physics C: Solid State Physics
Том 18
Первая страница L201
Последняя страница L207
Аффилиация M Weger; Racah Inst. of Phys., Hebrew Univ., Jerusalem, Israel
Аффилиация N F Mott; Racah Inst. of Phys., Hebrew Univ., Jerusalem, Israel
Выпуск 9

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