Thermal expansion and the law of corresponding states
P D Pathak; N G Vasavada; P D Pathak; Gujarat Univ., Ahmedabad, India; N G Vasavada; Gujarat Univ., Ahmedabad, India
Журнал:
Journal of Physics C: Solid State Physics
Дата:
1970-02-01
Аннотация:
The coefficients of linear expansion alpha for silver, copper and aluminium are determined by a sensitive method and compared with those of other workers. The reduced parameters alpha /( alpha )<sub>m/2</sub> and T/T<sub>m</sub> give a common curve for all metals. Here T<sub>m</sub> is the melting point and ( alpha )<sub>m/2</sub> is the value of alpha at T=<sup>1</sup>/<sub>2</sub>T<sub>m</sub>. The curve is a straight line within the approximate limits 0.2<T/T<sub>m</sub><0.45 and is found to deviate considerably from linearity at higher temperatures. Assuming that the deviation is due to defects, the energies of monovacancy formation in close-packed cubic metals are estimated and are found to agree excellently with the observed values.
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