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Автор A E Hughes
Дата выпуска 1970-03-01
dc.description It is proposed that the excited state of the F<sup>+</sup> centre in CaO is an example of a new type of Jahn-Teller effect, considered by O'Brien (1969) in which coupling to two different symmetries of vibrational mode occurs. This explanation is capable of removing the apparently puzzling inconsistency between Faraday rotation results on the 355.7 nm zero-phonon line and uniaxial stress splitting data on the same line. It is shown that the new interpretation presents a tenable solution of the problem provided the coupling energies (Jahn-Teller energies) of the excited orbital triplet state to E<sub>g</sub> and T<sub>2g</sub> vibrational modes are within about 70 cm<sup>-1</sup> of each other.
Формат application.pdf
Издатель Institute of Physics Publishing
Название A solution of the calcium oxide F<sup>+</sup> centre problem using a two mode Jahn-Teller effect)
Тип paper
DOI 10.1088/0022-3719/3/3/017
Print ISSN 0022-3719
Журнал Journal of Physics C: Solid State Physics
Том 3
Первая страница 627
Последняя страница 637
Аффилиация A E Hughes; UKAE Establ., Harwell, UK
Выпуск 3

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