Nuclear resonance of <sup>27</sup>Al in three rare earth aluminates from room temperature to 1.4K
D T Edmonds; G P Gill; D T Edmonds; Oxford Univ., UK; G P Gill; Oxford Univ., UK
Журнал:
Journal of Physics C: Solid State Physics
Дата:
1971-08-16
Аннотация:
From an analysis of the room temperature nuclear resonance of <sup>27</sup>Al principal values are obtained for the electric field gradient eq V<sub>zz</sub>/h and the anisotropy constant eta at an aluminium site for GdAlO<sub>3</sub> (0.589+or-0.01 MHz and 0.878), TbAlO<sub>3</sub>(0.890+or-0.01 MHz and 0.01 MHz and 0.613) and DyAlO<sub>3</sub> (1.30+or-0.03 MHz and 0.655). The directions of the principal axes of the electric field gradient relative to the crystal axes are obtained. At low temperatures the nuclear resonance of <sup>27</sup>Al is measured in GdAlO<sub>3</sub> in the paramagnetic region (T>3.87 K) and the antiferromagnetic region (1.4 K<T<3.87K). The results obtained are shown to agree with a simple model based on the currently held view of the ordered magnetic structure of this salt. There remains a large discrepancy between the magnitude of the observed internal magnetic field at an <sup>27</sup>Al site and that calculated assuming classical magnetic dipole coupling. The possibility of a large anisotropic transferred hyperfine interaction is discussed.
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