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Автор N L Peterson
Автор L W Barr
Автор A D Le Claire
Дата выпуска 1973-06-25
dc.description The isotope effect for diffusion of Ag<sup>105</sup> and Ag<sup>111</sup> has been measured at six temperatures in AgBr, two in AgCl, one in AgBr+0.08% CdBr<sub>2</sub>, and one in silver metal. The results for silver metal and cadmium-doped AgBr are consistent with the vacancy mechanism and a 'kinetic energy factor' Delta K equal to 0.86+or-0.05 and 0.66+or-0.02, respectively. A method of analysing the measurements in the pure silver halides is presented. The problem is more complex than for other systems studied to date because of the simultaneous operation of a vacancy and two types of interstitialcy migration processes in AgBr-type crystals. The equation for the mass effect of the total interstitialcy components is derived.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Isotope effect for silver diffusion in AgBr and AgCl
Тип paper
DOI 10.1088/0022-3719/6/12/005
Print ISSN 0022-3719
Журнал Journal of Physics C: Solid State Physics
Том 6
Первая страница 2020
Последняя страница 2039
Аффилиация N L Peterson; AERE, Harwell, Didcot, UK
Аффилиация L W Barr; AERE, Harwell, Didcot, UK
Аффилиация A D Le Claire; AERE, Harwell, Didcot, UK
Выпуск 12

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