Jahn-Teller effects in orbital triplets. I. Second-order contributions for D(T<sub>2</sub>) ions in cubic crystals coupled to E-type lattice distortions
M Abou-Ghantous; C A Bates; P E Chandler; K W H Stevens; M Abou-Ghantous; Univ. Nottingham, UK; C A Bates; Univ. Nottingham, UK; P E Chandler; Univ. Nottingham, UK; K W H Stevens; Univ. Nottingham, UK
Журнал:
Journal of Physics C: Solid State Physics
Дата:
1974-01-21
Аннотация:
Transformation methods are used to calculate the second-order contributions to the effective hamiltonian of a D(T<sub>2</sub>) ion coupled to E-type displacements in a cubic crystal. It is found that it is only possible to relate the first- and second-order Jahn-Teller reduction factors when a cluster model is used. For other lattice models, the parameters are unrelated. Finally, the orbital contribution to the magnetic susceptibility of a crystal containing delta (T<sub>2</sub>) ions is calculated.
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