Автор |
A J C Wilson |
Дата выпуска |
1970-09-01 |
dc.description |
The radial variation of intensity in reciprocal space is ordinarily the main source of displacement and broadening of powder diffraction profiles, and the usual tangent-plane approximation is adequate for the problem. When the main variation of intensity is perpendicular to the reciprocal radius vector a tangent-paraboloid approximation is necessary. For a layer structure with not too closely spaced random mistakes the centroid displacement of the hk0 reflections is approximately α(2d<sub>hk0</sub>σ)<sup>1/2</sup>/π<sup>2</sup>, where 2α is the probability of a mistake per unit distance, d<sub>hk0</sub> is the interplanar spacing of the reflection in question and σ is the range over which the profile is measured. The additional variance of the profile under the same conditions is approximately fraction one-thirdσ times the centroid displacement. More complex expressions are given, valid for somewhat larger values of α or smaller values of σ. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
Tangential contribution to centroid displacement and variance of powder diffraction profiles |
Тип |
note |
DOI |
10.1088/0022-3727/3/9/425 |
Electronic ISSN |
1361-6463 |
Print ISSN |
0022-3727 |
Журнал |
Journal of Physics D: Applied Physics |
Том |
3 |
Первая страница |
1403 |
Последняя страница |
1404 |
Аффилиация |
A J C Wilson; Department of Physics, University of Birmingham, PO Box 363, Birmingham 15 |
Выпуск |
9 |