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Автор D Hayashi
Автор W F L M Hoeben
Автор G Dooms
Автор E M van Veldhuizen
Автор W R Rutgers
Автор G M W Kroesen
Дата выпуска 2000-11-07
dc.description The phenol degradation processes by pulsed corona discharges are investigated under three kinds of discharge atmosphere (air, argon and oxygen). The temporal variations of the concentrations of phenol and the intermediate products are monitored by LIF spectroscopy. The species of the intermediate products are identified by spectral analysis. It is clarified that the oxidative gaseous reagents produced from O<sub>2</sub> and those from H<sub>2</sub>O degrade phenol to intermediate products with comparable degradation rates. The degradation via the reagents from H<sub>2</sub>O gives rise to the formation of molecules exhibiting fluorescence at 400-500 nm, in addition to dihydroxybenzene (DHB), while the degradation via the reagents from O<sub>2</sub> produces only DHB. The reagents from O<sub>2</sub> play an important role in the conversion of phenol to DHB.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Influence of gaseous atmosphere on corona-induced degradation of aqueous phenol
Тип paper
DOI 10.1088/0022-3727/33/21/315
Electronic ISSN 1361-6463
Print ISSN 0022-3727
Журнал Journal of Physics D: Applied Physics
Том 33
Первая страница 2769
Последняя страница 2774
Аффилиация D Hayashi; Faculty of Applied Physics, Eindhoven University of Technology, P O Box 513, 5600 MB Eindhoven, The Netherlands
Аффилиация W F L M Hoeben; Faculty of Applied Physics, Eindhoven University of Technology, P O Box 513, 5600 MB Eindhoven, The Netherlands
Аффилиация G Dooms; Faculty of Applied Physics, Eindhoven University of Technology, P O Box 513, 5600 MB Eindhoven, The Netherlands
Аффилиация E M van Veldhuizen; Faculty of Applied Physics, Eindhoven University of Technology, P O Box 513, 5600 MB Eindhoven, The Netherlands
Аффилиация W R Rutgers; Faculty of Applied Physics, Eindhoven University of Technology, P O Box 513, 5600 MB Eindhoven, The Netherlands
Аффилиация G M W Kroesen; Faculty of Applied Physics, Eindhoven University of Technology, P O Box 513, 5600 MB Eindhoven, The Netherlands
Выпуск 21

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