Vapor Pressures of Natural Neon and of the Isotopes <sup>20</sup>Ne and <sup>22</sup>Ne from the Triple Point to the Normal Boiling Point
George T Furukawa; George T Furukawa; National Bureau of Standards, Washington, DC, USA
Журнал:
Metrologia
Дата:
1972-01-01
Аннотация:
Apparatus design and procedures are described for the determination of the vapor pressures of naturally occurring neon (<sup>nat</sup>Ne) and the pure isotopes <sup>20</sup>Ne and <sup>22</sup>Ne from their triple points (TP) to their normal boiling points (NBP). The data have been fitted to vapor-pressure equations with root-mean-square deviations of ± 2.5 to ± 4.7 N/m<sup>2</sup> (± 0.019 to ± 0.035 mmHg). The TP pressures (P) and the TP and NBP temperatures (T) were found to be:TPNBPPT, KT, K<sup>nat</sup>Ne43332 ± 13 N/m<sup>2</sup> (325.02 ± 0.10 mmHg)24.553 ± 0.00127.096 ±0.001<sup>20</sup>Ne43326 ± 13 N/m<sup>2</sup> (324.97 ± 0.10 mmHg)24.540 ± 0.00127.084 ± 0.001<sup>22</sup>Ne43654 ± 13 N/m<sup>2</sup> (327.43 ± 0.10 mmHg24.687 ± 0.00127.211 ± 0.001(The temperatures are in terms of the NBS-1955 provisional temperature scale. The figures after the ± symbol indicate estimated uncertainties). The calculated vapor pressures of the isotopic <sup>nat</sup>Ne, based on Raoult's law of solution and the observed vapor pressures of the pure isotopes, are in agreement within the combined precision of the measurements with the observed values of <sup>nat</sup>Ne.
1.798Мб