The resistivity and thermoelectric power of liquid Ag-Pd alloys
R J Newport; B C Dupree; J E Enderby; R A Howe; R J Newport; Dept. of Phys., Univ. of Leicester, Leicester, UK; B C Dupree; Dept. of Phys., Univ. of Leicester, Leicester, UK; J E Enderby; Dept. of Phys., Univ. of Leicester, Leicester, UK; R A Howe; Dept. of Phys., Univ. of Leicester, Leicester, UK
Журнал:
Journal of Physics F: Metal Physics
Дата:
1981-12-01
Аннотация:
The resistivity ( rho ) and thermoelectric power (S) have been measured as functions of concentration and temperature for the liquid alloy system Ag-Pd. Comparison is made between the experimental results and the theoretical predictions of a nearly free electron model adapted for liquid transition metals. It is concluded that such a theory is unable to reproduce the gross features of the concentration dependence of rho and S even when concentration-dependent effective valencies are introduced. The close similarity between the concentration dependence of the resistivity and thermoelectric power of solid Ag-Pd alloys at high temperatures and that of the liquid alloys lends support to the alternative s-d scattering model proposed by Mott (1972).
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