The effect of paramagnetic impurities on proton spin relaxation in yttrium dihydride
M Belhoul; G A Styles; E F W Seymour; T -T Phua; R G Barnes; D R Torgeson; D T Peterson; M Belhoul; Dept. of Phys., Univ. of Warwick, Coventry, UK; G A Styles; Dept. of Phys., Univ. of Warwick, Coventry, UK; E F W Seymour; Dept. of Phys., Univ. of Warwick, Coventry, UK; T -T Phua; Dept. of Phys., Univ. of Warwick, Coventry, UK; R G Barnes; Dept. of Phys., Univ. of Warwick, Coventry, UK; D R Torgeson; Dept. of Phys., Univ. of Warwick, Coventry, UK; D T Peterson; Dept. of Phys., Univ. of Warwick, Coventry, UK
Журнал:
Journal of Physics F: Metal Physics
Дата:
1982-10-01
Аннотация:
Pulsed NMR measurements of the proton spin-lattice relaxation time, T<sub>1</sub>, in yttrium dihydride containing controlled amounts of gadolinium are reported over the temperature range 140-1250K. Addition of gadolinium produces a temperature-dependent relaxation contribution which is proportional to gadolinium concentration and gives rise to a subsidiary minimum on the low-temperature side of the main minimum due to proton-proton dipolar interactions. The results are interpreted in terms of a magnetic dipolar interaction between the Gd<sup>3+</sup> paramagnetic ions and the protons. The possibility that some of the diffusion data deduced from previous NMR measurements has been affected by the unsuspected presence of paramagnetic impurities is discussed.
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