Nuclear magnetic resonance of aluminium in intermetallic compounds of Ni-rich β-AlNi
J M Brettell; W S Hinshaw; J M Brettell; Dept. of Phys., Univ. of Nottingham, Nottingham, UK; W S Hinshaw; Dept. of Phys., Univ. of Nottingham, Nottingham, UK
Журнал:
Journal of Physics F: Metal Physics
Дата:
1976-06-01
Аннотация:
Measurements of Al<sup>27</sup> Knight shift, spin-lattice relaxation time line intensity and transient spin echo have been made on five alloys of beta -AlNi in the composition range 60.5 at.% Ni to 58.3 at.% Ni. For stoichiometric composition predominantly electron conduction has been assumed and an electron effective mass of (1.3+or-0.1) m has been calculated from the Knight shift and spin-lattice relaxation time measurements. The line intensity data give a nuclear 'wipeout' number for the satellite transitions of 104+or-10 for small departures from stoichiometry. This has been discussed in terms of the screening charge oscillations around those Ni atoms in excess of the stoichiometric composition.
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