Compressibilities and volume dependence of T<sub>c</sub> for eleven Chevrel phase superconductors
A W Webb; R N Shelton; A W Webb; Naval Res. Lab., Washington, DC, USA; R N Shelton; Naval Res. Lab., Washington, DC, USA
Журнал:
Journal of Physics F: Metal Physics
Дата:
1978-02-01
Аннотация:
Compressibility measurements up to 29.8 kbar (10 kbar=1 GPa) are presented for a number of superconducting ternary molybdenum sulphides and selenides as well as the binary compound Mo<sub>6</sub>Se<sub>8</sub>. The percent volume change ( Delta V/V<sub>0</sub>) exhibits a strong nonlinear dependence on applied pressure. Values of the bulk modulus (B<sub>0</sub>) and its first pressure derivative (B<sub>0</sub>') are obtained by fitting these data to the Murnaghan equation of state. This analysis reveals a small bulk modulus for each material, with values comparable to those found in simple s-p elements such as indium. The data are also utilised to convert previously measured pressure effects on the superconducting transition temperature into the more physically meaningful volume dependence of T<sub>c</sub>.
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