Автор |
D M S Bagguley |
Автор |
J H E Griffiths |
Дата выпуска |
1952-08-01 |
dc.description |
Paramagnetic resonance absorption in single crystals of the copper Tutton salts has been investigated at 3.10 cm wavelength between 90° k and room temperature. In salts diluted with zinc Tutton salt the hyperfine lines are clearly resolved at 90° k but broaden and merge into one another as the temperature is raised. From these measurements the spin-lattice relaxation time τ can be estimated and is found to be about 2×10<sup>-9</sup> sec It is found that 1/τ varies linearly with temperature between 150° k and 290° k An investigation of the crystalline field in the Tutton salts shows that for the concentrated salts the field has a strong rhombic component above 150° k, whilst in the salts diluted with zinc to less than 1% copper the crystalline field has tetragonal symmetry at 290° k, but the tetragonal axis lies in a plane perpendicular to that containing the tetragonal axis at 90° k. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
Paramagnetic Resonance and Spin-Lattice Relaxation Times in the Copper Tutton Salts |
Тип |
paper |
DOI |
10.1088/0370-1298/65/8/302 |
Print ISSN |
0370-1298 |
Журнал |
Proceedings of the Physical Society. Section A |
Том |
65 |
Первая страница |
594 |
Последняя страница |
603 |
Аффилиация |
D M S Bagguley; The Clarendon Laboratory, Oxford |
Аффилиация |
J H E Griffiths; The Clarendon Laboratory, Oxford |
Выпуск |
8 |