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Автор D M S Bagguley
Автор J H E Griffiths
Дата выпуска 1952-08-01
dc.description Paramagnetic resonance absorption in single crystals of the copper Tutton salts has been investigated at 3.10 cm wavelength between 90° k and room temperature. In salts diluted with zinc Tutton salt the hyperfine lines are clearly resolved at 90° k but broaden and merge into one another as the temperature is raised. From these measurements the spin-lattice relaxation time τ can be estimated and is found to be about 2×10<sup>-9</sup> sec It is found that 1/τ varies linearly with temperature between 150° k and 290° k An investigation of the crystalline field in the Tutton salts shows that for the concentrated salts the field has a strong rhombic component above 150° k, whilst in the salts diluted with zinc to less than 1% copper the crystalline field has tetragonal symmetry at 290° k, but the tetragonal axis lies in a plane perpendicular to that containing the tetragonal axis at 90° k.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Paramagnetic Resonance and Spin-Lattice Relaxation Times in the Copper Tutton Salts
Тип paper
DOI 10.1088/0370-1298/65/8/302
Print ISSN 0370-1298
Журнал Proceedings of the Physical Society. Section A
Том 65
Первая страница 594
Последняя страница 603
Аффилиация D M S Bagguley; The Clarendon Laboratory, Oxford
Аффилиация J H E Griffiths; The Clarendon Laboratory, Oxford
Выпуск 8

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