Properties of the Hydrogen Molecular Ion III: Oscillator Strengths of the 1sσ<sub>g</sub>-2pπ<sub>u</sub>, 2pσ<sub>u</sub>-3dπ<sub>g</sub> and 2pπ<sub>u</sub>-3dπ<sub>g</sub> Transitions
D R Bates; R T S Darling; S C Hawe; A L Stewart; D R Bates; Department of Applied Mathematics, Queen's University of Belfast; R T S Darling; Department of Applied Mathematics, Queen's University of Belfast; S C Hawe; Department of Applied Mathematics, Queen's University of Belfast; A L Stewart; Department of Applied Mathematics, Queen's University of Belfast
Журнал:
Proceedings of the Physical Society. Section A
Дата:
1953-12-01
Аннотация:
The oscillator strengths of the 1sσ<sub>g</sub>-2pπ<sub>u</sub>, 2pσ<sub>u</sub>-3dπ<sub>g</sub> and 2pπ<sub>u</sub>-3dπ<sub>g</sub> transitions of H<sub>2</sub><sup>+</sup> are calculated from the exact two-centre wave functions. A comparison is made with results obtained from the l.c.a.o. approximation, both the dipole length and the dipole velocity formulae being used. The polarizability of the normal ion perpendicular to the molecular axis is discussed briefly.
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