| Автор | S N Ghosh |
| Автор | A Sharma |
| Автор | Sharda Nand |
| Дата выпуска | 1962-01-01 |
| dc.description | Controlled reaction between active nitrogen and methylene chloride is performed in a dynamical flow system. The nitrogen is activated by a microwave discharge from an oscillator operating at a frequency of 2450 Mc/s. The spectrum of the N<sub>2</sub> discharge shows the first and second positive systems of N<sub>2</sub>, first negative system of N<sub>2</sub><sup>+</sup> and some atomic lines. The spectrum of the glow produced by the reaction between active nitrogen and methylene chloride shows the red and violet systems of CN and one band of CH at 4312 Å. The intensity variation of a CN band with the partial pressure of CH<sub>2</sub>Cl<sub>2</sub> is studied photometrically and the cross section of quenching of excited CN by CH<sub>2</sub>Cl<sub>2</sub> is found to be 1.8 × 10<sup>-14</sup> cm<sup>2</sup>.The mass-spectrometric analysis of the gas taken from the region where glow occurs shows HCl as one of the final products of the reaction. The mechanism of the reaction is discussed. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Controlled Rection between Active Nitrogen and Methylene Chloride |
| Тип | paper |
| DOI | 10.1088/0370-1328/79/1/325 |
| Print ISSN | 0370-1328 |
| Журнал | Proceedings of the Physical Society |
| Том | 79 |
| Первая страница | 207 |
| Последняя страница | 218 |
| Аффилиация | S N Ghosh; J. K. Institute of Applied Physics, University of Allahabad |
| Аффилиация | A Sharma; J. K. Institute of Applied Physics, University of Allahabad |
| Аффилиация | Sharda Nand; J. K. Institute of Applied Physics, University of Allahabad |
| Выпуск | 1 |
