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Автор G F J Garlick
Автор M Springford
Автор H Checinska
Дата выпуска 1963-07-01
dc.description Indium sesquisulphide (In<sub>2</sub>S<sub>3</sub>) has been synthesized from its constituent elements in a closed two-zone furnace system. The sulphur pressure is controlled by the zone temperatures. Both single crystals and polycrystalline specimens show infra-red emission at 90 °K with spectral maxima at 0 79 and 0.88 μm. Excitation is achieved using shorter wavelength radiation (0.5 to 0.7 μm). After excitation at low temperatures, warming in the dark produces thermoluminescence, peaks occurring at 113 °K and 126 °K. The peaks are very sharp and follow a form expected from a bimolecular trapping mechanism, the second peak at 126 °K corresponding to a trap depth of 0.35 eV. The frequency factor obtained is about 10<sup>14</sup> sec<sup>-1</sup> and leads to trap cross sections of the order of 10<sup>-12</sup> cm<sup>2</sup>, which indicates the `giant' nature of such traps. The possible origin of these traps in the cation defective crystal lattice is discussed.
Формат application.pdf
Издатель Institute of Physics Publishing
Название The Infra-red Emission of Indium Sesquisulphide
Тип paper
DOI 10.1088/0370-1328/82/1/304
Print ISSN 0370-1328
Журнал Proceedings of the Physical Society
Том 82
Первая страница 16
Последняя страница 22
Аффилиация G F J Garlick; Department of Physics, University of Hull
Аффилиация M Springford; Department of Physics, University of Hull
Аффилиация H Checinska; Department of Physics, University of Hull
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