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Автор J V Champion
Автор A Suddaby
Дата выпуска 1963-09-01
dc.description A theoretical calculation of the anisotropy of flow for carbon tetrachloride is made using the relative pair distribution determined by the Smoluchowski equation. A mean potential curve has been erected for carbon tetrachloride based on both experimental data and theoretical considerations and satisfying a stringent normalizing condition. These considerations determine the potential curve sufficiently precisely to allow it to be used with confidence for the calculation of anisotropy. The anisotropy is obtained in a form containing the friction constant as a factor so that comparison with the experimental value allows the value of the friction constant to be determined. The value found, namely 3 × 10<sup>12</sup> sec<sup>-1</sup>, is of the same order of magnitude as the minimum value for which the Smoluchowski equation is a reasonable approximation. This suggests that the latter equation, though not strictly valid, is still a useful approximation for some liquids.
Формат application.pdf
Издатель Institute of Physics Publishing
Название A Liquid Friction Constant from Flow Anisotropy
Тип paper
DOI 10.1088/0370-1328/82/3/308
Print ISSN 0370-1328
Журнал Proceedings of the Physical Society
Том 82
Первая страница 382
Последняя страница 392
Аффилиация J V Champion; Department of Physics, Sir John Cass College, London
Аффилиация A Suddaby; Department of Physics, Sir John Cass College, London
Выпуск 3

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