Автор |
J V Champion |
Автор |
A Suddaby |
Дата выпуска |
1963-09-01 |
dc.description |
A theoretical calculation of the anisotropy of flow for carbon tetrachloride is made using the relative pair distribution determined by the Smoluchowski equation. A mean potential curve has been erected for carbon tetrachloride based on both experimental data and theoretical considerations and satisfying a stringent normalizing condition. These considerations determine the potential curve sufficiently precisely to allow it to be used with confidence for the calculation of anisotropy. The anisotropy is obtained in a form containing the friction constant as a factor so that comparison with the experimental value allows the value of the friction constant to be determined. The value found, namely 3 × 10<sup>12</sup> sec<sup>-1</sup>, is of the same order of magnitude as the minimum value for which the Smoluchowski equation is a reasonable approximation. This suggests that the latter equation, though not strictly valid, is still a useful approximation for some liquids. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
A Liquid Friction Constant from Flow Anisotropy |
Тип |
paper |
DOI |
10.1088/0370-1328/82/3/308 |
Print ISSN |
0370-1328 |
Журнал |
Proceedings of the Physical Society |
Том |
82 |
Первая страница |
382 |
Последняя страница |
392 |
Аффилиация |
J V Champion; Department of Physics, Sir John Cass College, London |
Аффилиация |
A Suddaby; Department of Physics, Sir John Cass College, London |
Выпуск |
3 |