The Jahn-Teller coupling of 3d<sup>6</sup> ions in a cubic crystal
Mary C M O'Brien; Mary C M O'Brien; Department of Theoretical Physics, Clarendon Laboratory, Oxford
Журнал:
Proceedings of the Physical Society
Дата:
1965-10-01
Аннотация:
The effect of the Jahn-Teller coupling on the shape of the d ↔ d transition of a 3d<sup>6</sup> ion in a cubic crystal is calculated on a simplified model in which the kinetic energy of the nuclei is neglected in the excited state. The result is applied to Fe<sup>2+</sup> in MgO by the use of a modified Debye model, using data from compressional experiments. The predicted splitting of the d ↔ d transition is about half that actually observed. The reduction of the ground state g value by the Jahn-Teller coupling is small.
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