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Автор B D Padalia
Автор Gunadhor S Okram
Автор Om Prakash
Автор R Suba
Автор Sanjay Gupta
Автор S J Gurman
Автор J C Amiss
Дата выпуска 1998-12-01
dc.description Effects of the substitution of divalent A (Ca, Sr or Ba) ion in Ce excess non-superconducting compound, leading to revival of superconductivity, are studied by measuring absorption edges of all the cations with synchrotron radiation. It is found that in these NACCO samples, Cu exists mainly in the 2+ state; the weak pre-edge feature near the position is marginally affected due to ions. Except for the case of Ba doping, a fall in the intensity of the white line at the Cu K-edge is observed. This is attributed to a decrease in lattice oxygen content (oxygen vacancy creation) leading to an increase in electron carriers. It is noted that when the effective charge on Cu is , the -type samples are superconducting.
Формат application.pdf
Издатель Institute of Physics Publishing
Название X-ray absorption near edge structure study of -type revived superconducting compounds, (NACCO), A = Ca, Sr or Ba,
Тип paper
DOI 10.1088/0953-2048/11/12/005
Electronic ISSN 1361-6668
Print ISSN 0953-2048
Журнал Superconductor Science and Technology
Том 11
Первая страница 1381
Последняя страница 1385
Выпуск 12

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