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Автор Cai Zhen
Автор Li Li
Автор Zhihe Wang
Дата выпуска 1999-03-01
dc.description The oxygen in-diffusion processes in c-textured epitaxial thin films were monitored by in situ electrical resistivity measurements. The chemical diffusion coefficients were found to be sensitive to the oxygen content and varied greatly on crossing the phase transition point. The varying diffusivity could be divided into three ranges where different diffusion mechanisms work. Diffusivity was concentration independent in orthorhombic phase limits (interstitial mechanism), decreased as oxygen deficiency increased up to the point of the O-T phase transition, and then increased with increasing oxygen deficiency in the tetragonal phase (vacancy mechanism). The active energies of oxygen diffusion were obtained to be about and in tetragonal and orthorhombic phases respectively; these values were close to those of other authors. The magnitude of chemical diffusivity variation was within one order at the same temperature.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Diffusion mechanism of oxygen in orthorhombic and tetragonal -textured epitaxial thin films
Тип paper
DOI 10.1088/0953-2048/12/3/009
Electronic ISSN 1361-6668
Print ISSN 0953-2048
Журнал Superconductor Science and Technology
Том 12
Первая страница 158
Последняя страница 161
Аффилиация Cai Zhen; Shanghai Institute of Metallurgy, Chinese Academy of Sciences, 865 Changning Road, Shanghai 200050, People's Republic of China
Аффилиация Li Li; Shanghai Institute of Metallurgy, Chinese Academy of Sciences, 865 Changning Road, Shanghai 200050, People's Republic of China
Аффилиация Zhihe Wang; Shanghai Institute of Metallurgy, Chinese Academy of Sciences, 865 Changning Road, Shanghai 200050, People's Republic of China
Выпуск 3

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