Heat treatment studies on Bi-2212/Ag tapes fabricated using a powder-in-tube technique
K Thangaraj; A N Iyer; L Zhang; K Salama; K Thangaraj; Texas Center for Superconductivity, University of Houston, TX 77204, USA; A N Iyer; Texas Center for Superconductivity, University of Houston, TX 77204, USA; L Zhang; Texas Center for Superconductivity, University of Houston, TX 77204, USA; K Salama; Texas Center for Superconductivity, University of Houston, TX 77204, USA
Журнал:
Superconductor Science and Technology
Дата:
2000-07-01
Аннотация:
A powder-in-tube (PIT) process employing groove and flat rolling has been successfully used for the fabrication of Bi<sub>2</sub>Sr<sub>2</sub>CaCu<sub>2</sub>O<sub>x</sub> (Bi-2212)/Ag tapes. The tapes were melt processed at 890 °C, which was followed by controlled cooling to 855 °C in order to complete the phase formation. The effect of processing atmosphere (air versus oxygen) on the current transport properties, and microstructure were studied. The average J<sub>c</sub> at 4.2 K, self-field with 1 µV cm<sup>-1</sup> criteria, was higher for tapes processed in oxygen (5×10<sup>4</sup> A cm<sup>-2</sup>) compared to tapes processed in air (6.25×10<sup>3</sup> A cm<sup>-2</sup>). Microstructural analysis on the heat treated tapes revealed that the oxygen processed tapes had a higher Bi-2212 content, better grain alignment and smaller secondary phases compared to the tapes processed in air. Bubble defects, which severely deteriorate I<sub>c</sub> of the tapes, were more pronounced for tapes processed in oxygen. TEM studies on the Bi-2212-Ag interface illustrate the oxygen heat treated tapes to have sharp and straight interface compared to air processed tapes which exhibit a tendency to facet in the direction of [0 0 1]/[2 0 6].
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