Preparation and superconducting properties of Y-Ba-Cu-O films on oxide polycrystalline substrates by chemical vapour deposition
H Kurosawa; H Yamane; T Hirai; K Watanabe; S Awaji; N Kobayashi; Y Muto; H Kurosawa; Riken Co., Kumagaya, Japan; H Yamane; Riken Co., Kumagaya, Japan; T Hirai; Riken Co., Kumagaya, Japan; K Watanabe; Riken Co., Kumagaya, Japan; S Awaji; Riken Co., Kumagaya, Japan; N Kobayashi; Riken Co., Kumagaya, Japan; Y Muto; Riken Co., Kumagaya, Japan
Журнал:
Superconductor Science and Technology
Дата:
1991-05-01
Аннотация:
Y-Ba-Cu-O superconducting films were prepared on Y<sub>2</sub>O<sub>3</sub>-stabilized ZrO<sub>2</sub>(YSZ), MgO and Al<sub>2</sub>O<sub>3</sub> polycrystalline substrates by chemical vapour deposition using beta -diketone metal chelates as sources. The c-axis of YBa<sub>2</sub>Cu<sub>3</sub>O<sub>y</sub> was mainly oriented perpendicular to the plane of the films obtained above 800 degrees C. The films deposited on YSZ and MgO at 850 degrees C showed zero resistivity at 90 K and 87 K, respectively. The superconducting transition temperature of 71 K was the highest among the transition temperatures of the films deposited on Al<sub>2</sub>O<sub>3</sub>. The critical current density (J<sub>c</sub>) of the film on YSZ was 8.0*10<sup>3</sup> A cm<sup>-2</sup> and that of the film on MgO was 1.0*10<sup>4</sup> A cm<sup>-2</sup> at 77.3 K and 0 T. J<sub>c</sub> measured at 77.3 K under an applied magnetic field of 15 T parallel to the film planes was 44 A cm<sup>-2</sup> for the film on YSZ and 27 A cm<sup>-2</sup> for the film on MgO. The temperature gradients of the upper critical field (-dB<sub>c2</sub>/dT) determined by the definition of zero resistivity for upper critical field (-dB<sub>c2</sub>/dT) determined by the definition of zero resistivity for the film prepared on the YSZ substrate were 4.7 T K<sup>-1</sup> and 1.0 T K<sup>-1</sup> when the magnetic field was parallel and perpendicular to the film plane, respectively.
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