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Автор Ye-Xin Chen
Автор Jihua Zhang
Автор Ziliang Wu
Дата выпуска 1992-08-01
dc.description C-axis-oriented YBa<sub>2</sub>Cu<sub>3</sub>O<sub>7- delta </sub> films produced by electron beam and thermal evaporation are composed of mosaic blocks. The deoxygenated YBa<sub>2</sub>Cu<sub>3</sub>O<sub>x</sub> (x=6.1-6.2) films were annealed in an oxygen atmosphere. The change of oxygen concentration in the films during the annealing process was detected by the diffraction peak site of the (0011) peak. Applying the theory of lattice diffusion to analyse the oxygen-in-diffusion in the films, the authors obtain the activation energies for oxygen diffusion in the tetragonal and orthorhombic phases, which are 1.15 and 1.23 eV respectively. The change of shape of (00 11) diffraction peaks indicates that there is a coexistent range of two phases near the transition point. The difference between single crystals and c-axis film is that there are many mosaic boundaries in the c-axis film. A mosaic boundary acts as a short-circuit for oxygen diffusion and makes the diffusion time, during which equilibrium oxygen concentration is attained in the films, decrease greatly.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Oxygen diffusion in c-axis-oriented YBa<sub>2</sub>Cu<sub>3</sub>O<sub>x</sub> films
Тип paper
DOI 10.1088/0953-2048/5/8/001
Electronic ISSN 1361-6668
Print ISSN 0953-2048
Журнал Superconductor Science and Technology
Том 5
Первая страница 463
Последняя страница 466
Аффилиация Ye-Xin Chen; Shanghai Inst. of Metall., Acad. Sinica, China
Аффилиация Jihua Zhang; Shanghai Inst. of Metall., Acad. Sinica, China
Аффилиация Ziliang Wu; Shanghai Inst. of Metall., Acad. Sinica, China
Выпуск 8

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