Автор |
A N Maljuk |
Автор |
G A Emel'chenko |
Автор |
I I Zver'kova |
Автор |
A V Kosenko |
Дата выпуска |
1994-08-01 |
dc.description |
The La<sub>2</sub>Cu<sub>2</sub>O<sub>5</sub> and La<sub>1-x</sub>Sr<sub>x</sub>CuO<sub>2.5- delta </sub> crystallization regions have been investigated in the system La<sub>2</sub>O<sub>3</sub>SrO-CuO at fixed molar ratio La<sub>2</sub>O<sub>3</sub>:CuO=1:8 in the range of SrO concentrations from 0.0 to 5.5 mol%. It has been shown that Sr is non-soluble in La<sub>2</sub>Cu<sub>2</sub>O<sub>5</sub> and the crystallization region of this phase is limited by the SrO concentration in the melt approximately=1 mol%. When the SrO concentration in the melt exceeds approximately=1% mol%, the La<sub>1-x</sub>Sr<sub>x</sub>CuO<sub>2.5- delta </sub> phase crystallization takes place below 1050 degrees C. The Sr lower solubility limit in La<sub>1-x</sub>Sr<sub>x</sub>CuO<sub>2.5- delta </sub> is found to be x approximately=0.05 atoms/FU. This compound does not exist if the Sr content is lower. The tentative projections of the primary crystallization phase boundaries of CuO, La<sub>2</sub>Cu<sub>2</sub>O<sub>5</sub>, La<sub>1-x</sub>Sr<sub>x</sub>CuO<sub>2.5- delta </sub> and La<sub>2-x</sub>Sr<sub>x</sub>CuO<sub>4- delta </sub> phases on the La<sub>2</sub>O<sub>3</sub>SrO-CuO composition triangles have been constructed. |
Формат |
application.pdf |
Издатель |
Institute of Physics Publishing |
Название |
Crystallization regions of the La<sub>2</sub>Cu<sub>2</sub>O<sub>5</sub> and La<sub>1-x</sub>Sr<sub>x</sub>CuO<sub>2.5- delta </sub> phases in the La<sub>2</sub>O<sub>3</sub>-SrO-CuO system |
Тип |
paper |
DOI |
10.1088/0953-2048/7/8/012 |
Electronic ISSN |
1361-6668 |
Print ISSN |
0953-2048 |
Журнал |
Superconductor Science and Technology |
Том |
7 |
Первая страница |
596 |
Последняя страница |
601 |
Аффилиация |
A N Maljuk; Inst. of Solid State Phys., Acad. of Sci., Chernogolovka, Russia |
Аффилиация |
G A Emel'chenko; Inst. of Solid State Phys., Acad. of Sci., Chernogolovka, Russia |
Аффилиация |
I I Zver'kova; Inst. of Solid State Phys., Acad. of Sci., Chernogolovka, Russia |
Аффилиация |
A V Kosenko; Inst. of Solid State Phys., Acad. of Sci., Chernogolovka, Russia |
Выпуск |
8 |