High-energy resonances in the T<sub>1</sub>(⊗)( in <sub>g</sub>(⊕)τ<sub>2g</sub>) Jahn-Teller system with spin-orbit coupling
C C Chancey; M C M O'Brien; C C Chancey; Dept. of Theor. Phys., Oxford Univ., UK; M C M O'Brien; Dept. of Theor. Phys., Oxford Univ., UK
Журнал:
Journal of Physics: Condensed Matter
Дата:
1989-01-09
Аннотация:
The T<sub>1</sub>(X)( in <sub>g</sub>(+) tau <sub>2g</sub>) Jahn-Teller system is studied under conditions of equally strong spin-orbit and linear vibronic interactions. Several unitary transformations are introduced which simplify the Hamiltonian, and a representation involving the lowest few total angular momentum eigenstates is set up. This procedure allows for the resonance energies and intensities to be solved for in a manner which improves with increasing coupling strengths. To complement this analysis, an approximate analytical solution is also developed. Comparison with previous matrix diagonalisation results shows good agreement.
1.221Мб