| Автор | P S Salmon |
| Автор | G J Herdman |
| Автор | J Lindgren |
| Автор | M C Read |
| Автор | M Sandstrom |
| Дата выпуска | 1989-06-05 |
| dc.description | The technique of high-resolution, incoherent quasi-elastic neutron scattering (IQENS) is applied to a 1.790 molal (mol kg<sup>-1</sup>) solution of Cr(ClO<sub>4</sub>)<sub>3</sub> at 26+or-1 degrees C. The results are consistent with a dynamic hydration number of six water molecules, each having a Cr<sup>3+</sup>-water-proton binding time described by the limit tau <sub>1</sub>>or approximately=5*10<sup>-9</sup> s. The results do not show a second shell of water protons in slow exchange with the cation, which implies a Cr<sup>3+</sup> to second-shell water-proton binding time that is <5*10<sup>-9</sup> s. Values for the water-proton translational self-diffusion coefficients are presented. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | An incoherent quasi-elastic neutron scattering study on the dynamics of aqueous Cr<sup>3+</sup> perchlorate solutions |
| Тип | paper |
| DOI | 10.1088/0953-8984/1/22/007 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 1 |
| Первая страница | 3459 |
| Последняя страница | 3468 |
| Аффилиация | P S Salmon; Sch. of Phys., East Anglia Univ., Norwich, UK |
| Аффилиация | G J Herdman; Sch. of Phys., East Anglia Univ., Norwich, UK |
| Аффилиация | J Lindgren; Sch. of Phys., East Anglia Univ., Norwich, UK |
| Аффилиация | M C Read; Sch. of Phys., East Anglia Univ., Norwich, UK |
| Аффилиация | M Sandstrom; Sch. of Phys., East Anglia Univ., Norwich, UK |
| Выпуск | 22 |
