Transition-metal monoxides: band or Mott insulators? Angle-resolved photoemission results for CoO
N B Brookes; D S -L Law; D R Warburton; P L Wincott; G Thornton; N B Brookes; Dept. of Chem., Manchester Univ., UK; D S -L Law; Dept. of Chem., Manchester Univ., UK; D R Warburton; Dept. of Chem., Manchester Univ., UK; P L Wincott; Dept. of Chem., Manchester Univ., UK; G Thornton; Dept. of Chem., Manchester Univ., UK
Журнал:
Journal of Physics: Condensed Matter
Дата:
1989-07-03
Аннотация:
Evidence of itinerant band-like behaviour of the Co 3d states in paramagnetic CoO has been observed in CoO(001) angle-resolved photoemission spectra. Two d bands are identified, which disperse 0.4 eV and 1.7 eV between Gamma and X. In broad terms the results are consistent with a recently proposed model of the electronic structure in which the insulating gap arises largely from an exchange potential perturbation of the one-electron band structure.
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