Exchange and crystal-field interactions of Ho<sup>3+</sup> in GdAl<sub>2</sub>: a single-crystal NMR study
D F McMorrow; M A H McCausland; Z -P Han; J S Abell; D F McMorrow; Schuster Lab., Manchester Univ., UK; M A H McCausland; Schuster Lab., Manchester Univ., UK; Z -P Han; Schuster Lab., Manchester Univ., UK; J S Abell; Schuster Lab., Manchester Univ., UK
Журнал:
Journal of Physics: Condensed Matter
Дата:
1989-12-25
Аннотация:
The hyperfine splitting of holmium, as a dilute (1%) substituent in ferromagnetic GdAl<sub>2</sub> has been studied by spin-echo NMR at liquid helium temperatures. The measurements were made on oriented single crystals, with fields up to 8 T applied along twofold, threefold and fourfold crystallographic symmetry axes. The field dependence of the hyperfine splitting is interpreted in terms of the standard three-parameter mean-field model for lanthanide ions at sites of cubic symmetry. The crystal-field coefficients are found to be 30% to 40% smaller than those for pure HoAl<sub>2</sub>; moreover, the molecular field seen by the holmium ion is more than 20% below the lower bound derived from a current model of exchange in RAl<sub>2</sub> compounds. These unexpected results are strikingly confirmed by a recent analysis of FMR data on a dilute Ho:GdAl<sub>2</sub> alloy. Possible explanations are considered.
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