| Автор | K Holliday |
| Автор | N B Manson |
| Дата выпуска | 1989-02-20 |
| dc.description | This paper describes the first observation of persistent spectral hole-burning in actinide-ion-doped crystals. Spectral hole-burning in three zero-phonon lines at 652.1 nm, 658.4 nm and 659.1 nm in SrWO<sub>4</sub>:U and one zero-phonon line at 654.4 nm in BaWO<sub>4</sub>:U is reported. The holes display quadratic Zeeman shifts. Also when the field is along the (110) direction the holes are split into two indicating the presence of two crystallographically equivalent sites of C<sub>2</sub> symmetry. This is explained in terms of U<sup>6+</sup> ions substituting for W<sup>6+</sup> but having two equilibrium positions displaced in alternate directions along the c axis from the substitutional site. As well as narrow holes there are broad anti-holes, resulting in an unchanged integrated absorption that the hole-burning is photophysical. The mechanism is attributed to the reorientation of the U<sup>6+</sup> between the two sites. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Spectral hole-burning in uranium-doped tungstates |
| Тип | paper |
| DOI | 10.1088/0953-8984/1/7/016 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 1 |
| Первая страница | 1339 |
| Последняя страница | 1352 |
| Аффилиация | K Holliday; Res. Sch. of Phys. Sci., Australian Nat. Univ., Canberra, ACT, Australia |
| Аффилиация | N B Manson; Res. Sch. of Phys. Sci., Australian Nat. Univ., Canberra, ACT, Australia |
| Выпуск | 7 |
