Neutron scattering studies of the structure and lattice dynamics of a solid solution of hydrogen in -manganese
V K Fedotov; V E Antonov; K Cornell; G Grosse; A I Kolesnikov; V V Sikolenko; V V Sumin; F E Wagner; H Wipf
Журнал:
Journal of Physics: Condensed Matter
Дата:
1998-06-22
Аннотация:
A solid solution of hydrogen in , with x = 0.073, was prepared at 623 K and a hydrogen pressure of 0.85 GPa. A profile analysis of the neutron diffraction patterns measured at 225 K and at 300 K showed that hydrogen in randomly occupies the interstitial positions 12e (0, 0, 0.538) of the host lattice. An inelastic neutron scattering study of at 90 K revealed a pronounced peak at 6.4 meV and a rather broad optical hydrogen band with peaks at 73, 105 and 123 meV. The splitting of the optical band into three different modes agrees with the low symmetry, 2, of the 12e hydrogen sites. A tentative interpretation is given for the peak at 6.4 meV.
201.2Кб