| Автор | Thorsten Koslowski |
| Автор | Uta Beck |
| Дата выпуска | 1999-04-19 |
| dc.description | With reference to dense ionic liquids like the alkali metal-alkali halide melts, , we present a study of the distribution of the excess electronic charge x in Coulomb systems with electronic degrees of freedom. Within the mean-spherical approximation to the restricted primitive model of ionic liquids, we demonstrate the stability of systems that exhibit a maximum separation of cationic charges, . The results are verified and illustrated by Monte Carlo simulations. We discuss the implications of the principle of maximum charge separation for the electronic structure and the thermodynamics of dense ionic liquids, possible additional applications and its limitations due to the neglect of quantum effects. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Charge separation in Coulomb liquids: mean-spherical approximation and Monte Carlo simulation |
| Тип | paper |
| DOI | 10.1088/0953-8984/11/15/008 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 11 |
| Первая страница | 3019 |
| Последняя страница | 3028 |
| Аффилиация | Thorsten Koslowski; Institut für Physikalische Chemie I, Universität Karlsruhe, Kaiserstraße 12, D-76128 Karlsruhe, Germany |
| Аффилиация | Uta Beck; Institut für Physikalische Chemie I, Universität Karlsruhe, Kaiserstraße 12, D-76128 Karlsruhe, Germany |
| Выпуск | 15 |
