| Автор | R F C Claridge |
| Автор | N S Lees |
| Автор | W C Tennant |
| Автор | C J Walsby |
| Дата выпуска | 1999-05-03 |
| dc.description | Two previously unreported Ti<sup>3+</sup> paramagnetic centres have been observed in zircon (zirconium silicate, ZrSiO<sub>4</sub>) and studied by X-band electron paramagnetic resonance at 10 K. The first of these is shown to arise from a Ti<sup>3+</sup> electron-trap centre where Ti substitutes into one of the Si<sup>4+</sup> sites, point group symmetry 2m (D<sub>2d</sub>), of the tetragonal crystal. A full spin-Hamiltonian analysis of the centre is given. The second centre arises from Ti<sup>3+</sup> substituting for Zr<sup>4+</sup> in the lattice and interacting with a 100% spin-I = ½ nucleus, probably <sup>31</sup>P, in a nearby lattice site, thought to be a next-nearest-neighbour Si site. The point group symmetry of the site of this centre is 2 (C<sub>2</sub>). |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Two Ti<sup>3+</sup> centres studied by X-band electron paramagnetic resonance at 10 K in zircon |
| Тип | paper |
| DOI | 10.1088/0953-8984/11/17/315 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 11 |
| Первая страница | 3571 |
| Последняя страница | 3580 |
| Аффилиация | R F C Claridge; Department of Chemistry, University of Canterbury, Private Bag 4800, Christchurch, New Zealand |
| Аффилиация | N S Lees; Department of Chemistry, University of Canterbury, Private Bag 4800, Christchurch, New Zealand |
| Аффилиация | W C Tennant; Department of Chemistry, University of Canterbury, Private Bag 4800, Christchurch, New Zealand |
| Аффилиация | C J Walsby; Department of Chemistry, University of Canterbury, Private Bag 4800, Christchurch, New Zealand |
| Выпуск | 17 |
