| Автор | Kristin Kirschbaum |
| Автор | Anthony Martin |
| Автор | Damon A Parrish |
| Автор | A Alan Pinkerton |
| Дата выпуска | 1999-06-14 |
| dc.description | The rare earth vanadate TbVO<sub>4</sub>, undergoes a crystallographic phase transition below 33 K induced by a cooperative Jahn-Teller effect. Twinning of the crystal occurs upon this transition from the tetragonal high temperature phase to the orthorhombic low temperature phase resulting in a domain structure. Single crystal x-ray analyses of the tetragonal and the twinned orthorhombic phase verify a reduction in the site symmetry of the Tb ion from D<sub>2d</sub> (m2-dodecahedral) for the high temperature phase to D<sub>2</sub> (222-distorted dodecahedral) for the low temperature phase. Concomitantly, the space group symmetry is lowered from D<sup>19</sup><sub>4h</sub> (I4<sub>1</sub>/amd) to D<sup>24</sup><sub>2h</sub> (Fddd). The twinned orthorhombic phase is described as domains related to each other by a 180° rotation about the orthorhombic [110] axis. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Cooperative Jahn-Teller induced phase transition of TbVO<sub>4</sub>: single crystal structure analyses of the tetragonal high temperature phase and the twinned orthorhombic phase below 33 K |
| Тип | paper |
| DOI | 10.1088/0953-8984/11/23/302 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 11 |
| Первая страница | 4483 |
| Последняя страница | 4490 |
| Аффилиация | Kristin Kirschbaum; 2801 W Bancroft Street, Department of Chemistry, University of Toledo, Toledo, OH 43606, USA |
| Аффилиация | Anthony Martin; 2801 W Bancroft Street, Department of Chemistry, University of Toledo, Toledo, OH 43606, USA |
| Аффилиация | Damon A Parrish; 2801 W Bancroft Street, Department of Chemistry, University of Toledo, Toledo, OH 43606, USA |
| Аффилиация | A Alan Pinkerton; 2801 W Bancroft Street, Department of Chemistry, University of Toledo, Toledo, OH 43606, USA |
| Выпуск | 23 |
