Unusual broadening and splitting of the K ≈ 0 transverse-optical phonon in hcp Mg at high pressure
Helmut Olijnyk; Helmut Olijnyk; Department of Earth Sciences, University of Oxford, Oxford OX1 3PR, UK
Журнал:
Journal of Physics: Condensed Matter
Дата:
1999-08-30
Аннотация:
The transverse-optical Γ-point phonon mode was studied in the stability range of hcp Mg up to 50 GPa by Raman spectroscopy. A positive frequency shift is observed with increasing pressure in good agreement with recent theoretical studies using the pseudo-potential method. Unexpected broadening and splitting of this mode occurs under pressure. The separation increases to 20 cm<sup>-1</sup> at 50 GPa. Slight structural modifications, anharmonic effects or an unusual pressure-induced dispersion around the Γ-point, not observed in other hcp metals so far, are suggested as possible explanations for the splitting.
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