Optical properties of europium ions in SrB<sub>2</sub>O<sub>4</sub> crystal
Hyo Jin Seo; Byung Kee Moon; Beang Ju Kim; Jeong Bae Kim; Taiju Tsuboi
Журнал:
Journal of Physics: Condensed Matter
Дата:
1999-10-04
Аннотация:
We investigate absorption, emission and excitation properties of an SrB<sub>2</sub>O<sub>4</sub>:Eu crystal grown from the melt using the Czochralski method. Eu<sup>2+</sup> absorption and Eu<sup>3+</sup> emission spectra are obtained. The five broad absorption bands peaking at 344, 288, 259, 235 and 212 nm correspond to the transitions from the 4f<sup>7</sup>(<sup>8</sup>S<sub>7/2</sub>) ground state to the excited states of the 4f<sup>6</sup>5d configuration of Eu<sup>2+</sup>. Several zero-phonon lines for the different 4f<sup>6</sup>(<sup>7</sup>F<sub>J</sub>) levels of the lowest 4f<sup>6</sup>5d excited state are observed in the absorption spectrum measured at 10 K. The deep-orange luminescence in the 578-640 nm region is due to the transition from the <sup>5</sup>D<sub>0</sub> excited state to the <sup>7</sup>F<sub>J</sub> (J = 0, 1 and 2) states of Eu<sup>3+</sup>.Eu<sup>2+</sup> does not give rise to luminescence, even at 10 K, because of the photoionization in the excited state, followed by a nonradiative return to the ground state of Eu<sup>2+</sup>. The strong emission due to the <sup>5</sup>D<sub>0</sub> <sup>7</sup>F<sub>0</sub> transition and the existence of different sites of Eu<sup>3+</sup> for Sr<sup>2+</sup> are explained by the charge compensation and structural characteristic of SrB<sub>2</sub>O<sub>4</sub>.
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