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Автор Andrei Rogalev
Автор José Goulon
Автор Christian Brouder
Дата выпуска 1999-02-01
dc.description High-resolution sulphur K-edge x-ray absorption near-edge structure spectra have been recorded for europium and gadolinium monosulphides. A comparison of the experimental spectra with the element-projected partial density of unoccupied states calculated using a spin-polarized linear muffin-tin orbital method revealed a rather good agreement. Our analysis suggests that there is a strong hybridization of the 4f and 5d orbitals of the rare earths with the p orbitals of the sulphur which also contribute to the conduction band. The strong d-p and f-p interactions result in a large sulphur p-band polarization which has been confirmed experimentally by the detection of a strong x-ray magnetic circular dichroism signal at the S K edge in EuS.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Sulphur K-edge x-ray absorption fine-structure studies of EuS and GdS
Тип paper
DOI 10.1088/0953-8984/11/4/019
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 11
Первая страница 1115
Последняя страница 1121
Выпуск 4

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