Ferroelastic symmetry changes in the perovskite PbFeY<sub>0.5</sub>Ta<sub>0.5</sub>O<sub>3</sub>
Alessandra Geddo Lehmann; Philippe Sciau
Журнал:
Journal of Physics: Condensed Matter
Дата:
1999-02-08
Аннотация:
The ferroelastic symmetry changes of the lead-based complex perovskite PbFeY<sub>0.5</sub>Ta<sub>0.5</sub>O<sub>3</sub> are investigated by means of single crystal x-ray diffraction and observations in polarized light microscopy at different temperatures. The position of the 400 and 222 cubic reflections is followed between 80 K and 300 K. Results indicate the presence of two structural transitions at about 270 K and 220 K. Such temperatures define the stability range of three different phases. The high-temperature phase (T > 270 K) is the optically anomalous paraelectric prototype, the optical symmetry of which is uniaxial (tetragonal) in spite of the diffractometric (pseudo)cubic symmetry. The intermediate derived phase (270 K > T > 220 K) is tetragonal. This tetragonal phase coexists with a monoclinic one for 220 K > T > 200 K. Below 200 K only the monoclinic phase is stable. The (pseudo)cubic-to-tetragonal transition seems to be of the second order. The tetragonal-to-monoclinic one is of the first order.
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