Phase equilibria in a model of low-salt suspensions of charged colloids
René van Roij; Robert Evans; René van Roij; H H Wills Physics Laboratory, Royal Fort, University of Bristol, Bristol BS8 1TL, UK; Robert Evans; H H Wills Physics Laboratory, Royal Fort, University of Bristol, Bristol BS8 1TL, UK
Журнал:
Journal of Physics: Condensed Matter
Дата:
1999-12-20
Аннотация:
We calculate phase diagrams of low-salt suspensions of charged colloidal particles using a recently proposed effective one-component Hamiltonian for the colloids (van Roij R, Dijkstra M and Hansen J-P 1999 Phys. Rev. E 59 2010). This Hamiltonian consists of the purely repulsive pairwise Derjaguin, Landau, Verwey, and Overbeek (DLVO) potential and density-dependent volume terms. The latter play a crucial role in driving phase transitions at salt concentrations of the order of 10 µM or lower. We find phase diagrams that exhibit gas-liquid coexistence with upper and lower critical points, and, for sufficiently large surface charge densities, upper and lower gas-liquid-solid triple points. A connection between the Debye-Hückel theory for simple electrolytes and the DLVO theory for colloidal suspensions is made.
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