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Автор José A Cuesta
Автор Yuri Martínez-Ratón
Дата выпуска 1999-12-20
dc.description In this article we introduce depletion in asymmetric mixtures within the context of density functional theory. As in the definition of the interaction potentials, it is convenient to work in a semi-grand ensemble at constant chemical potential of the small particles. The free-energy functional can then be mapped onto that of a one-component effective fluid. This method is applied to the fluid of parallel hard cubes, which is studied in the limit of infinite asymmetry. The phase behaviour of this fluid is shown and discussed in terms of the general phase behaviour of additive mixtures of hard particles.
Формат application.pdf
Издатель Institute of Physics Publishing
Название A density functional approach to depletion interaction
Тип paper
DOI 10.1088/0953-8984/11/50/305
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 11
Первая страница 10107
Последняя страница 10118
Аффилиация José A Cuesta; Grupo Interdisciplinar de Sistemas Complicados, Departamento de Matemáticas, Universidad Carlos III de Madrid, 28911-Leganés, Madrid, Spain
Аффилиация Yuri Martínez-Ratón; Grupo Interdisciplinar de Sistemas Complicados, Departamento de Matemáticas, Universidad Carlos III de Madrid, 28911-Leganés, Madrid, Spain
Выпуск 50

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