Dielectric relaxation in PAN/EC/PC (poly-(acrylonitrile)/ethylene carbonate/propylene carbonate) mixtures
H Eliasson; B-E Mellander; L Sjögren
Журнал:
Journal of Physics: Condensed Matter
Дата:
1999-12-20
Аннотация:
Dielectric measurements have been performed on a series of samples consisting of poly-(acrylonitrile) (PAN) mixed with the plasticizers ethylene carbonate (EC) and propylene carbonate (PC) in various proportions. The spectra obtained show characteristic features such as a linear ln() variation, a horizontal inflection point and double minima, which are predicted within the A<sub>4</sub>-scenario of the mode-coupling theory. We find very good agreement with the theoretical results in the relevant frequency range. The experimental spectra are found to satisfy a scaling behaviour, and the resulting master curves are in good agreement with the theoretical predictions.
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