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Автор Shosuke Mochizuki
Автор Mie Sasaki
Автор Raphael Ruppin
Дата выпуска 1999-02-15
dc.description We have applied the time-resolved and space-resolved spectroscopies of vapour zones produced by gradual thermal evaporation in a noble gas to study the electronic properties and stability of hydrogenated clusters and microcrystals. Optical extinction spectra of lithium vapour zones in pure Ar gas and Ar - H<sub>2</sub> gas mixture atmospheres confined at various pressures were obtained. Some comparisons of the observed spectra with those predicted theoretically indicate that hydrogenated clusters Li<sub>n</sub>H<sub>m</sub> are to be found near the vapour source, while lithium microcrystals coated with LiH shells are to be found far away from the vapour source. Electron localization around hydrogen atoms and the hydrogenation mechanism of lithium particles are also discussed.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Optical spectra of lithium vapour zones produced by thermal evaporation in hydrogenating atmosphere
Тип paper
DOI 10.1088/0953-8984/11/6/026
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 11
Первая страница 1621
Последняя страница 1629
Аффилиация Shosuke Mochizuki; Department of Physics, College of Humanities and Sciences, Nihon University, 3-25-40 Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan
Аффилиация Mie Sasaki; Department of Physics, College of Humanities and Sciences, Nihon University, 3-25-40 Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan
Аффилиация Raphael Ruppin; Department of Physics, College of Humanities and Sciences, Nihon University, 3-25-40 Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan
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