| Автор | S Dixit |
| Автор | W C K Poon |
| Автор | J Crain |
| Автор | S Dixit |
| Автор | W C K Poon |
| Дата выпуска | 2000-05-29 |
| dc.description | High-resolution Raman spectroscopy was used to study methanol-water mixtures over the whole concentration range. We report a highly non-linear dependence of the carbon-oxygen and carbon-hydrogen stretching frequencies with composition. The difference between the polarized and depolarized frequencies of the carbon-oxygen stretching mode (non-coincidence effect) was also measured. Taken together, the data suggest a global picture of the progressive hydration of methanol: water first breaks up the molecular chains which exist in pure methanol, and then completely hydrates the hydroxyl groups before solvating the hydrophobic methyl groups. |
| Формат | application.pdf |
| Издатель | Institute of Physics Publishing |
| Название | Hydration of methanol in aqueous solutions: a Raman spectroscopic study |
| Тип | lett |
| DOI | 10.1088/0953-8984/12/21/103 |
| Electronic ISSN | 1361-648X |
| Print ISSN | 0953-8984 |
| Журнал | Journal of Physics: Condensed Matter |
| Том | 12 |
| Первая страница | L323 |
| Последняя страница | L328 |
| Аффилиация | S Dixit; Department of Physics and Astronomy, The University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ, UK |
| Аффилиация | W C K Poon; Department of Physics and Astronomy, The University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ, UK |
| Аффилиация | J Crain; Department of Physics and Astronomy, The University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ, UK |
| Аффилиация | S Dixit; Department of Physics and Astronomy, The University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ, UK |
| Аффилиация | W C K Poon; Department of Physics and Astronomy, The University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ, UK |
| Выпуск | 21 |
