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Автор A A Gippius
Автор E N Morozova
Автор D F Khozeev
Автор A N Vasil'ev
Автор M Baenitz
Автор G Dhalenne
Автор A Revcolevschi
Дата выпуска 2000-02-14
dc.description Nuclear quadrupole resonance results on the inorganic spin-Peierls compound CuGeO<sub>3</sub> were re-examined using a single crystal and enhanced resolution. A clear splitting of <sup>63,65</sup> Cu NQR lines of about 250 kHz at 4.2 K was observed. Such a splitting has not been previously seen in Cu NQR spectra measured on polycrystalline samples of CuGeO<sub>3</sub> (Itoh M et al 1995 Phys. Rev. B 52 3410, Kikuchi et al 1994 J. Phys. Soc. Japan 63 872). The mean frequency of the Cu doublet is in agreement with the Cu NQR frequency observed on powder samples. The splitting does not disappear with increasing temperature above T<sub>sP</sub> exhibiting only a slight kink at around 16 K. This points to a non-magnetic origin of the splitting which can be attributed to existence of at least two non-equivalent Cu crystal sites in CuGeO<sub>3</sub> structure, as predicted by precise x-ray study and EPR measurements (Hidaka M et al 1997 J. Phys.: Condens. Matter 9 809, Yamada I et al 1996 J. Phys.: Condens. Matter 8 2625).
Формат application.pdf
Издатель Institute of Physics Publishing
Название Non-equivalence of Cu crystal sites in CuGeO<sub>3</sub> as evidenced by NQR
Тип lett
DOI 10.1088/0953-8984/12/6/101
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 12
Первая страница L71
Последняя страница L75
Выпуск 6

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