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Автор Richard Kerner
Автор Gerardo G Naumis
Дата выпуска 2000-02-28
dc.description We present a model of the glass transition viewed as the agglomeration and growth of clusters forming a covalent network. The creation of new layers of atoms on the rims of the clusters is treated in a probabilistic way as a linear transformation (encoded in what is called a stochastic matrix ) of a vector whose components represent the probability distribution of various sites found on the rim. The asymptotic limit of the statistics of sites in the network is given by the matrix eigenvector with eigenvalue equal to one. The model reproduces the modified Gibbs-DiMarzio equation with a system parameter that is comparable to the one observed experimentally for many chalcogenide glasses. Some other features of the glass transition process, like the form of the specific heat, are also obtained.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Stochastic matrix description of the glass transition
Тип paper
DOI 10.1088/0953-8984/12/8/306
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 12
Первая страница 1641
Последняя страница 1648
Выпуск 8

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