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Автор Doriano Brogioli
Автор Alberto Vailati
Автор Marzio Giglio
Дата выпуска 2000-02-28
dc.description Concentration fluctuations in a homogeneous mixture are in general small and confined to the molecular lengthscale. It has been recently predicted that stressed fluids should exhibit anomalously large fluctuations. We will show here that anomalously large fluctuations also occur when macroscopic concentration gradients relax to the uniform state via diffusion. The measurements have been taken by low angle static light scattering and shadowgraphs. We find that at larger wavevectors the amplitude of the fluctuations diverges as q <sup>-4</sup> . It is also found that gravity stabilizes at a constant value the fluctuations below a critical wavevector. We will present data on a mixture close to a consolution critical point. Recent results will also be presented on ordinary liquid mixtures, a polymer and a protein solution. These new results have been obtained by means of a quantitative shadowgraph technique. They confirm that giant fluctuations are always associated with mass flow due to diffusion across a macroscopic gradient.
Формат application.pdf
Издатель Institute of Physics Publishing
Название Giant fluctuations in diffusion processes
Тип paper
DOI 10.1088/0953-8984/12/8A/305
Electronic ISSN 1361-648X
Print ISSN 0953-8984
Журнал Journal of Physics: Condensed Matter
Том 12
Первая страница A39
Последняя страница A46
Аффилиация Doriano Brogioli; Istituto Nazionale per la Fisica della Materia and Dipartimento di Fisica, Università di Milano, via Celoria 16, Milano, Italy
Аффилиация Alberto Vailati; Istituto Nazionale per la Fisica della Materia and Dipartimento di Fisica, Università di Milano, via Celoria 16, Milano, Italy
Аффилиация Marzio Giglio; Istituto Nazionale per la Fisica della Materia and Dipartimento di Fisica, Università di Milano, via Celoria 16, Milano, Italy
Выпуск 8A

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