Attraction or repulsion between charged colloids? A connection with Debye-Hückel theory
René van Roij; René van Roij; H H Wills Physics Laboratory, Royal Fort, University of Bristol, Bristol BS8 1TL, UK
Журнал:
Journal of Physics: Condensed Matter
Дата:
2000-02-28
Аннотация:
We discuss the phase behaviour of suspensions of charged colloidal particles, specifically at low salt concentrations. The total free energy F of a three-component system of charged colloids and positive and negative salt ions can be expressed as F = F <sub>DLVO</sub> +F <sub>0</sub> , where F <sub>DLVO</sub> is the free energy of a one-component system of colloidal particles interacting via the DLVO pair potential, and F <sub>0</sub> consists of density-dependent contributions from the salt ions. We argue that F <sub>0</sub> drives a gas-liquid spinodal at low salt concentrations, in accordance with several experimental observations. The underlying mechanism is equivalent to that of the well-established gas-liquid transition in simple electrolytes. The present theory connects directly the classic linearized Poisson-Boltzmann theories for simple electrolytes (Debye-Hückel) and colloidal suspensions (DLVO).
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