Ligand positions and crystal field parameters for Cr<sup>3+</sup> at tetragonal sites ion MgO
Y Y Yeung; Y Y Yeung; Dept. of Appl. Phys., Hong Kong Polytech., Hong Kong
Журнал:
Journal of Physics: Condensed Matter
Дата:
1990-03-12
Аннотация:
Ligand positions for Cr<sup>3+</sup> at tetragonal sites in MgO are calculated from a lattice relaxation model. Using these ligand positions in conjunction with the parameters previously derived from the Cr<sup>3+</sup>:Al<sub>2</sub>O<sub>3</sub> system, the author obtains the tetragonal crystal field parameters and the splittings of the low-lying energy levels for the present Cr<sup>3+</sup> system. These results are compared with some experimental data and some fallacious calculations found in the literature are pointed out.
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