Freezing of binary hard-disc alloys. II. The fluid-disordered crystal transition
Hong Xu; M Baus; Hong Xu; Fac. des Sci., Campus Plaine, Univ. Libre de Bruxelles, Belgium; M Baus; Fac. des Sci., Campus Plaine, Univ. Libre de Bruxelles, Belgium
Журнал:
Journal of Physics: Condensed Matter
Дата:
1990-07-02
Аннотация:
For pt.I see ibid., vol.21, p.3165 (1988). The density-functional theory of freezing is extended to the case of binary mixtures of hard discs viewed as a simple model for monolayers adsorbed on a smooth substrate. The theory is applied to the fluid-disordered crystal transition. The results are similar to those already obtained for the three-dimensional case: when the ratio of diameters is lowered, the phase diagram changes rapidly from a spindle, over a lower azeotrope to an eutectic diagram. Evidence is also found for the existence of a two-dimensional analogue of the empirical Hume-Rothery rule.
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